Why is Wurtz reaction not preferred for the preparation of alkan
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What effect does branching of an alkane chain has on its boiling point ?


Branching of an alkane chain makes the molecules more compact and brings various atoms closer. As a result, the molecular size decreases. This decreases the surface area and therefore the magnitude of Vander Waal's forces also decreases. Hence the boiling point of the alkane decreases with branching.

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In the alkane H3C - CH2 -C(CH3)2 -CH2 - CH(CH3)2, identify 1°, 2°, 3° carbon atoms and give the H atoms bounded to each one of these.


Write the structure of the given compound in expanded form.



15H attached to five 1° carbons
4H attached to two 2° carbons
1H attached to one 3° carbon

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For the following compounds, write structural formulas and IUPAC names for all possible isomers having the number of double or triple bond as indicated:
left parenthesis straight i right parenthesis space space straight C subscript 4 straight H subscript 8 left parenthesis one space double space bond right parenthesis
left parenthesis ii right parenthesis space straight C subscript 5 straight H subscript 8 space left parenthesis one space triple space bond right parenthesis


(a) Isomers of C4H8, having one double bond are:





(b) Isomers of C5H8 having one triple bond are:






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Suggest the name of a Lewis acid other than anhydrous aluminium chloride which can be used during ethylation of benzene.


Another Lewis acid other than anhydrous aluminium chloride is Anhydrous FeCl3, SnCl4, BF3 etc. 
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Why is Wurtz reaction not preferred for the preparation of alkanes containing odd number of carbon atoms? Illustrate your answer bytaking one example.


In order to prepare alkane with an odd number of carbon atoms, two different haloalkanes are needed; one with an odd number and the other with an even number of carbon atoms. For example, bromoethane and I-bromopropane will give pentane as a result of the reaction.



Butane product will also be formed when the numbers participating in the reaction react separately. For example, bromoethane will give butane and 1-bromopropane will give rise to hexane. 



Thus, a mixture of butane, pentane and hexane will be formed. It will be quite difficult to separate the individual components from the mixture.
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